Cookies Policy

The website of the University of Cádiz uses its own and third-party cookies to carry out analysis of use and measurement of traffic, as well as to allow the correct functioning in social networks, and in this way to improve your browsing experience.

If you want to configure cookies, press the button Customize Cookies. You can also access the cookie settings at any time from the corresponding link in the footer.

For more information about cookies you can consult the Cookies policy from the website of the University of Cádiz.

Cookies customization

The website of the University of Cádiz uses its own and third-party cookies to carry out analysis of use and measurement of traffic, as well as to allow the correct functioning in social networks, and in this way to improve your browsing experience.

For more information about cookies you can consult the Cookies policy from the website of the University of Cádiz. You can also access the cookie settings at any time from the corresponding link in the footer.

You can configure the website cookies according to their purpose:

  • Statistical analysis

    Third-party cookies (Google Analytics) are used on this site that allow the number of users to be quantified anonymously (personal data will never be obtained to identify the user) and thus be able to analyze the use made by users of our service, in order to improve the browsing experience and offer our content optimally.

  • Social networks

    Third-party cookies are used on this website that allow the proper functioning of some social networks (mainly YouTube and Twitter) without using any personal data of the user.

UniversidaddeCádiz
FQM137 Estabilidad y Mecanismo de Reacciones Inorgánicas


Información ORCID de GARCIA BASALLOTE, MANUEL


Biografía


Researcher at the Materials Science, Metallurgical Engineering and Inorganic Chemistry Department, Universidad de Cádiz


Empleo


Universidad de Cádiz: Cádiz, Andalucía, España



Obras


Spin-Crossing in the (Z)-Selective Alkyne Semihydrogenation Mechanism Catalyzed by Mo3S4 Clusters: A Density Functional Theory Exploration

2024 | JOURNAL_ARTICLE

DOI: 10.1021/acs.inorgchem.3c03057

Mostrar Detalles




Characterization of a Ferryl Flip in Electronically Tuned Nonheme Complexes. Consequences in Hydrogen Atom Transfer Reactivity

2023 | JOURNAL_ARTICLE

DOI: 10.1002/anie.202211361

EID: 2-s2.0-85143271882

Mostrar Detalles




Efficient (Z)-selective semihydrogenation of alkynes catalyzed by air-stable imidazolyl amino molybdenum cluster sulfides

2023 | JOURNAL_ARTICLE

DOI: 10.1039/D2QI02755K

Mostrar Detalles




Efficient (Z)-selective semihydrogenation of alkynes catalyzed by air-stable imidazolyl amino molybdenum cluster sulfides

2023 | JOURNAL_ARTICLE

DOI: 10.1039/d2qi02755k

EID: 2-s2.0-85150593118

Mostrar Detalles




Fe(ii) complexes of pyridine-substituted thiosemicarbazone ligands as catalysts for oxidations with hydrogen peroxide

2023 | JOURNAL_ARTICLE

DOI: 10.1039/D3DT02442C

Mostrar Detalles




Base-Free Catalytic Hydrogen Production from Formic Acid Mediated by a Cubane-Type Mo3S4 Cluster Hydride

2022 | JOURNAL_ARTICLE

DOI: 10.1021/acs.inorgchem.2c02540

EID: 2-s2.0-85140270371

Mostrar Detalles




Bifunctional W/NH Cuboidal Aminophosphino W3S4 Cluster Hydrides: The Puzzling Behaviour behind the Hydridic‐Protonic Interplay

2021 | JOURNAL_ARTICLE

DOI: 10.1002/ejic.202100684

EID: 2-s2.0-85116824547

Mostrar Detalles




Spin State Tunes Oxygen Atom Transfer towards FeIVO Formation in FeII Complexes

2021 | JOURNAL_ARTICLE

DOI: 10.1002/chem.202004921

EID: 2-s2.0-85101475163

Mostrar Detalles




Catalytic Hydrogenation of Azobenzene in the Presence of a Cuboidal Mo3S4 Cluster via an Uncommon Sulfur-Based H2 Activation Mechanism

2021 | JOURNAL_ARTICLE

DOI: 10.1021/acscatal.0c05299

EID: 2-s2.0-85099153423

Mostrar Detalles




Benchmarking of DFT methods using experimental free energies and volumes of activation for the cycloaddition of alkynes to cuboidal Mo3S4 clusters

2020 | JOURNAL_ARTICLE

DOI: 10.1002/qua.26353

EID: 2-s2.0-85087176578

Mostrar Detalles




Salen‑manganese complexes for controlling ROS damage: Neuroprotective effects, antioxidant activity and kinetic studies

2020 | JOURNAL_ARTICLE

DOI: 10.1016/j.jinorgbio.2019.110918

EID: 2-s2.0-85075042784

Parte de ISBN: 18733344 01620134

Mostrar Detalles




Proton-assisted air oxidation mechanisms of iron(ii) bis-thiosemicarbazone complexes at physiological pH: a kinetico-mechanistic study

2019 | JOURNAL_ARTICLE

DOI: 10.1039/c9dt03557e

EID: 2-s2.0-85074872130

Parte de ISBN: 14779234 14779226

Mostrar Detalles




Pitfalls in the ABTS Peroxidase Activity Test: Interference of Photochemical Processes

2018 | JOURNAL_ARTICLE

DOI: 10.1021/acs.inorgchem.8b02525

EID: 2-s2.0-85057845533

Parte de ISBN: 1520510X 00201669

Mostrar Detalles




Coordination Chemistry of Cu2+ Complexes of Small N-Alkylated Tetra-azacyclophanes with SOD Activity

2018 | JOURNAL_ARTICLE

DOI: 10.1021/acs.inorgchem.8b01492

EID: 2-s2.0-85052860163

Parte de ISBN: 1520510X 00201669

Mostrar Detalles




Cuboidal Mo3S4 Clusters as a Platform for Exploring Catalysis: A Three-Center Sulfur Mechanism for Alkyne Semihydrogenation

2018 | JOURNAL_ARTICLE

DOI: 10.1021/acscatal.8b02254

EID: 2-s2.0-85049849785

Parte de ISBN: 21555435

Mostrar Detalles




Acid‐Triggered O−O Bond Heterolysis of a Nonheme FeIII(OOH) Species for the Stereospecific Hydroxylation of Strong C−H Bonds

2018 | JOURNAL_ARTICLE

DOI: 10.1002/chem.201704851

EID: 2-s2.0-85040573297

Parte de ISBN: 15213765 09476539

Mostrar Detalles




Methylation as an effective way to generate SOD-activity in copper complexes of scorpiand-like azamacrocyclic receptors

2018 | JOURNAL_ARTICLE

DOI: 10.1016/j.ica.2017.08.044

EID: 2-s2.0-85029233298

Parte de ISBN: 00201693

Mostrar Detalles




Studies on the Reactivity of the [W3S4Br3(edpp)3]+ [edpp = (2‐aminoethyl)diphenylphosphine] Cluster Cation towards Bases: The Active Role of the Amino Group

2017 | JOURNAL_ARTICLE

DOI: 10.1002/ejic.201700641

EID: 2-s2.0-85034994154

Parte de ISBN: 10990682 14341948

Mostrar Detalles




Iron(II) Complexes with Scorpiand-Like Macrocyclic Polyamines: Kinetico-Mechanistic Aspects of Complex Formation and Oxidative Dehydrogenation of Coordinated Amines

2017 | JOURNAL_ARTICLE

DOI: 10.1021/acs.inorgchem.6b03070

EID: 2-s2.0-85018489294

Parte de ISBN: 1520510X 00201669

Mostrar Detalles




Kinetic Analysis and Mechanism of the Hydrolytic Degradation of Squaramides and Squaramic Acids

2017 | JOURNAL_ARTICLE

DOI: 10.1021/acs.joc.6b02963

EID: 2-s2.0-85013167925

Parte de ISBN: 15206904 00223263

Mostrar Detalles




Computational Insights Into the Reactivity at the Sulfur Atoms of M3S4 (M = Mo, W) Clusters: The Mechanism of [3 + 2] Cycloaddition With Alkynes

2017 | BOOK

DOI: 10.1016/bs.adioch.2017.01.003

EID: 2-s2.0-85018678723

Mostrar Detalles




Hydroxylated phosphines as ligands for chalcogenide clusters: Self assembly, transformations and stabilization

2017 | JOURNAL_ARTICLE

DOI: 10.1515/pac-2017-0105

EID: 2-s2.0-85017302494

Mostrar Detalles




Pb2+ complexes of small-cavity azamacrocyclic ligands: Thermodynamic and kinetic studies

2017 | JOURNAL_ARTICLE

DOI: 10.1039/c7dt00680b

EID: 2-s2.0-85021695608

Parte de ISBN: 14779234 14779226

Mostrar Detalles




Cycloaddition of alkynes to diimino Mo3S4 cubane-type clusters: A combined experimental and theoretical approach

2016 | JOURNAL_ARTICLE

DOI: 10.1039/c6nj01787h

EID: 2-s2.0-84984873637

Mostrar Detalles




Exceedingly fast oxygen atom transfer to olefins via a catalytically competent nonheme iron species

2016 | JOURNAL_ARTICLE

DOI: 10.1002/anie.201601396

EID: 2-s2.0-84981764242

Mostrar Detalles




Kinetics Aspects of the Reversible Assembly of Copper in Heterometallic Mo3CuS4 Clusters with 4,4′-Di-tert-butyl-2,2′-bipyridine

2016 | JOURNAL_ARTICLE

DOI: 10.1021/acs.inorgchem.6b01878

EID: 2-s2.0-84990058828

Mostrar Detalles




Correlation between the molecular structure and the kinetics of decomposition of azamacrocyclic copper(II) complexes

2015 | JOURNAL_ARTICLE

DOI: 10.1039/c5dt00408j

EID: 2-s2.0-84928657993

Parte de ISBN: 14779234 14779226

Mostrar Detalles




Equilibrium, Kinetic, and Computational Studies on the Formation of Cu2+ and Zn2+ Complexes with an Indazole-Containing Azamacrocyclic Scorpiand: Evidence for Metal-Induced Tautomerism

2015 | JOURNAL_ARTICLE

DOI: 10.1021/ic5029004

EID: 2-s2.0-84923207260

Parte de ISBN: 1520510X 00201669

Mostrar Detalles




Mechanism of [3+2] Cycloaddition of Alkynes to the [Mo3S4(acac)(3)(py)(3)][PF6] Cluster

2015 | JOURNAL_ARTICLE

DOI: 10.1002/chem.201405518

EID: 2-s2.0-84921836159

Parte de ISBN: 15213765 09476539

Mostrar Detalles




On the Critical Effect of the Metal (Mo vs. W) on the [3+2] Cycloaddition Reaction of M3S4 Clusters with Alkynes: Insights from Experiment and Theory

2015 | JOURNAL_ARTICLE

DOI: 10.1002/chem.201502644

EID: 2-s2.0-84943457626

Mostrar Detalles




Synthesis and Structure of Trinuclear W3S4 Clusters Bearing Aminophosphine Ligands and Their Reactivity toward Halides and Pseudohalides

2015 | JOURNAL_ARTICLE

DOI: 10.1021/ic5025313

EID: 2-s2.0-84921523538

Parte de ISBN: 1520510X 00201669

Mostrar Detalles




Trapping a Highly Reactive Nonheme Iron Intermediate That Oxygenates Strong C-H Bonds with Stereoretention

2015 | JOURNAL_ARTICLE

DOI: 10.1021/jacs.5b09904

EID: 2-s2.0-84952837151

Mostrar Detalles




Equilibrium and kinetics studies on bibrachial lariat aza-crown/Cu(II) systems reveal different behavior associated with small changes in the structure

2014 | JOURNAL_ARTICLE

DOI: 10.1016/j.ica.2013.12.020

EID: 2-s2.0-84892767576

Mostrar Detalles




Speciation-controlled incipient wetness impregnation: A rational synthetic approach to prepare sub-nanosized and highly active ceria-zirconia supported gold catalysts

2014 | JOURNAL_ARTICLE

DOI: 10.1016/j.jcat.2014.07.001

EID: 2-s2.0-84906685614

Parte de ISBN: 10902694 00219517

Mostrar Detalles




The role of hydroxo-bridged dinuclear species and the influence of "innocent" buffers in the reactivity of cis-[Co-III(cyclen)(H2O)(2)](3+) and [Co-III(tren)(H2O)(2)](3+) complexes with biologically relevant ligands at physiological pH

2014 | JOURNAL_ARTICLE

DOI: 10.1039/c4dt01003e

EID: 2-s2.0-84903467022

Parte de ISBN: 14779234 14779226

Mostrar Detalles




Equilibrium and kinetic studies on complex formation and decomposition and the movement of Cu2+metal ions within polytopic receptors

2013 | JOURNAL_ARTICLE

DOI: 10.1039/c3dt32220c

EID: 2-s2.0-84875768626

Mostrar Detalles




Influence of the ligand alkyl chain length on the solubility, aqueous speciation, and kinetics of substitution reactions of water-soluble M 3S4 (M = Mo, W) clusters bearing hydroxyalkyl diphosphines

2013 | JOURNAL_ARTICLE

DOI: 10.1021/ic400897y

EID: 2-s2.0-84881185732

Mostrar Detalles




Kinetic and DFT studies on the mechanism of C-S bond formation by alkyne addition to the [Mo3S4(H2O)9] 4+ cluster

2013 | JOURNAL_ARTICLE

DOI: 10.1021/ic4023344

EID: 2-s2.0-84890638500

Mostrar Detalles




A DFT and TD-DFT approach to the understanding of statistical kinetics in substitution reactions of M 3Q 4 (M=Mo, W; Q=S, Se) cuboidal clusters

2012 | JOURNAL_ARTICLE

DOI: 10.1002/chem.201102629

EID: 2-s2.0-84859582217

Mostrar Detalles




Copper(ii) complexes of quinoline polyazamacrocyclic scorpiand-type ligands: X-ray, equilibrium and kinetic studies

2012 | JOURNAL_ARTICLE

DOI: 10.1039/c2dt30223c

EID: 2-s2.0-84859802099

Mostrar Detalles




The solution chemistry of Cu2+-tren complexes revisited: Exploring the role of species that are not trigonal bipyramidal

2012 | JOURNAL_ARTICLE

DOI: 10.1002/ejic.201200075

EID: 2-s2.0-84861180909

Mostrar Detalles




Water-soluble Mo 3S 4 clusters bearing hydroxypropyl diphosphine ligands: Synthesis, crystal structure, aqueous speciation, and kinetics of substitution reactions

2012 | JOURNAL_ARTICLE

DOI: 10.1021/ic300517g

EID: 2-s2.0-84862550093

Mostrar Detalles




Kinetic, DFT and TD-DFT studies on the mechanism of stabilization of pyramidal H 3PO 3 at the [Mo 3M′S 4(H 2O) 10] 4+ clusters (M′ = Pd, Ni)

2011 | JOURNAL_ARTICLE

DOI: 10.1039/c1dt10625b

EID: 2-s2.0-80052096135

Mostrar Detalles




Chiral [Mo3S4H3(diphosphine) 3]+ hydrido clusters and study of the effect of the metal atom on the kinetics of the acid-assisted substitution of the coordinated hydride: Mo VS W

2010 | JOURNAL_ARTICLE

DOI: 10.1021/ic100381u

EID: 2-s2.0-77954127445

Mostrar Detalles




Hydrogen and copper ion induced molecular reorganizations in two new scorpiand-like ligands appended with pyridine rings

2010 | JOURNAL_ARTICLE

DOI: 10.1021/ic100609h

EID: 2-s2.0-77954992835

Mostrar Detalles




Site specific ligand substitution in cubane-type Mo3FeS 44+ clusters: Kinetics and mechanism of reaction and isolation of mixed ligand Cl/SPh complexes

2010 | JOURNAL_ARTICLE

DOI: 10.1039/b924801c

EID: 2-s2.0-77950203748

Mostrar Detalles




Striking medium effects on the kinetics of decomposition of macrocyclic Cu2+ complexes: Additional considerations to be taken when designing Copper-64 radiopharmaceuticals

2010 | JOURNAL_ARTICLE

DOI: 10.1016/j.inoche.2010.07.013

EID: 2-s2.0-77956926822

Mostrar Detalles




Structural reorganisation in polytopic receptors revealed by kinetic studies

2010 | JOURNAL_ARTICLE

DOI: 10.1039/c0cc01393e

EID: 2-s2.0-77955799789

Mostrar Detalles




The role of solvent on the mechanism of proton transfer to hydride complexes: The case of the [W3PdS4H3CdHiPe3(CO)] + cubane cluster

2010 | JOURNAL_ARTICLE

DOI: 10.1002/chem.200902233

EID: 2-s2.0-75949103227

Mostrar Detalles




Combined kinetic and DFT studies on the stabilization of the pyramidal form of H3PO2 at the heterometal site of [Mo 3M′S4(H2O)10]4+ clusters (M′ = Pd, Ni)

2009 | JOURNAL_ARTICLE

DOI: 10.1039/b817509h

EID: 2-s2.0-60649100010

Mostrar Detalles




Dihydrogen complexes: Striking effect of ion pairing to BF4- on the rotation of coordinated dihydrogen and the 19F relaxation time

2009 | JOURNAL_ARTICLE

DOI: 10.1039/b906330g

EID: 2-s2.0-68149144344

Mostrar Detalles




Geometric isomerism in pentacoordinate Cu2+ complexes: Equilibrium, kinetic, and density functional theory studies reveal the existence of equilibrium between square pyramidal and trigonal bipyramidal forms for a tren-derived ligand

2009 | JOURNAL_ARTICLE

DOI: 10.1021/ic8013078

EID: 2-s2.0-60849124264

Mostrar Detalles




Mechanistic aspects of the chemistry of mononuclear CrIII complexes with pendant-arm macrocyclic ligands and formation of discrete Cr III/FeII and CrIII/FeII/Co III cyano-bridged mixed valence compounds

2009 | JOURNAL_ARTICLE

DOI: 10.1039/b909151c

EID: 2-s2.0-70350393217

Mostrar Detalles




Synthesis, protonation and CuII complexes of two novel isomeric pentaazacyclophane ligands: Potentiometric, DFT, kinetic and AMP recognition studies

2009 | JOURNAL_ARTICLE

DOI: 10.1002/ejic.200800576

EID: 2-s2.0-58249095038

Mostrar Detalles




Synthesis, reactivity, and kinetics of substitution in W 3PdSe4 cuboidal clusters. A reexamination of the kinetics of substitution of the related W3S4 cluster with thiocyanate

2009 | JOURNAL_ARTICLE

DOI: 10.1021/ic802150x

EID: 2-s2.0-65349145907

Mostrar Detalles




Unprecedented Solvent-assisted reactivity of hydrido W3CuS 4 cubane clusters: The Non-innocent behaviour of the Cluster-core unit

2009 | JOURNAL_ARTICLE

DOI: 10.1002/chem.200802473

EID: 2-s2.0-65349128145

Mostrar Detalles




Equilibrium and kinetic properties of CuII cyclophane complexes: The effect of changes in the macrocyclic cavity caused by changes in the substitution at the aromatic ring

2008 | JOURNAL_ARTICLE

DOI: 10.1002/ejic.200701109

EID: 2-s2.0-53349147363

Mostrar Detalles




Kinetic Study on Molecular Movements Induced by pH Gradients

2008 | JOURNAL_ARTICLE

Mostrar Detalles




Sol-gel materials with trapped trinuclear class-II mixed-valence macrocyclic complexes that mimic their solution redox behaviour

2008 | JOURNAL_ARTICLE

DOI: 10.1039/b710963f

EID: 2-s2.0-38949107953

Mostrar Detalles




Catalytic effect of a second H3PO2 in the mechanism of stabilisation of the unstable pyramidal tautomer of H3PO 2 coordinated at [Mo3S4M′] clusters (M′ = Ni, Pd)

2007 | JOURNAL_ARTICLE

DOI: 10.1039/b704990k

EID: 2-s2.0-34447640015

Mostrar Detalles




Crucial role of anions on the deprotonation of the cationic dihydrogen complex trans-[FeH(η2-H2)(dppe)2] +

2007 | JOURNAL_ARTICLE

DOI: 10.1021/ja070939l

EID: 2-s2.0-34249077037

Mostrar Detalles




Dinitrogen Complexes of Iron(II) with (1,2-Ethanediyldinitrilo)Tetraacetate and Trans-(1,2-Cyclohexanediyldinitrilo)Tetraacetate

2007 | BOOK

DOI: 10.1002/9780470132555.ch60

EID: 2-s2.0-85050191966

Mostrar Detalles




Hydrogen and copper ion-induced molecular reorganizations in scorpionand-like ligands. A potentiometric, mechanistic, and solid-state study

2007 | JOURNAL_ARTICLE

DOI: 10.1021/ic700643n

EID: 2-s2.0-34547232645

Mostrar Detalles




Synthesis, crystal structure, aqueous speciation, and kinetics of substitution reactions in a water-soluble Mo3S4 cluster bearing hydroxymethyl diphosphine ligands

2007 | JOURNAL_ARTICLE

DOI: 10.1021/ic701082p

EID: 2-s2.0-34548629592

Mostrar Detalles




A combined stopped-flow, electrospray ionization mass spectrometry and31P NMR study on the acetic acid-mediated fragmentation of the hydroxo-chalcogenide cluster [W3Se4(OH)3(dmpe)3]+ (dmpe = 1,2-bis(dimethylphosphanyl)ethane) to yield the dinuclear [W2Se2(µ-Se)2(µ-CH3CO2)(dmpe)2]+ complex

2006 | JOURNAL_ARTICLE

DOI: 10.1039/b611274a

EID: 2-s2.0-33845350153

Mostrar Detalles




New insights into the mechanism of proton transfer to hydride complexes: Kinetic and theoretical evidence showing the existence of competitive pathways for protonation of the cluster [W3S4H3(dmpe) 3]+ with acids

2006 | JOURNAL_ARTICLE

DOI: 10.1002/chem.200500695

EID: 2-s2.0-32044467659

Mostrar Detalles




Synthesis and Cu(II) coordination of two new hexaamines containing alternated propylenic and ethylenic chains: Kinetic studies on pH-driven metal ion slippage movements

2006 | JOURNAL_ARTICLE

DOI: 10.1016/j.ica.2006.01.030

EID: 2-s2.0-33645920637

Mostrar Detalles




Synthesis of the novel [W3PdS4H3(dmpe) 3(CO)]+ cubane cluster and kinetic studies on the substitution of coordinated hydrides in acidic media

2006 | JOURNAL_ARTICLE

DOI: 10.1021/ic052184u

EID: 2-s2.0-33746481005

Mostrar Detalles




The structure of ([W3Q4X3(dmpe) 3]+, Y-) ion pairs (Q = S, Se; X = H, OH, Br; Y = BF4, PF6, dmpe = Me2PCH2CH 2PMe2) in dichloromethane solution and the effect of ion-pairing on the kinetics of proton transfer to the hydride cluster...

2006 | JOURNAL_ARTICLE

DOI: 10.1021/ic0520770

EID: 2-s2.0-33748863921

Mostrar Detalles




Ag(I) complexes with alkylidene-bis(2-aminopyrimidines) as building units for discrete metallomacrocyclic frames. A structural and solution study

2005 | JOURNAL_ARTICLE

DOI: 10.1039/b508260a

EID: 2-s2.0-29144450688

Mostrar Detalles




Mechanism of the Reaction of the [W3S4H 3(dmpe)3]+ Cluster with Acids: Evidence for the Acid-Promoted Substitution of Coordinated Hydrides and the Effect of the Attacking Species on the Kinetics of Protonation of the Metal-Hydride Bonds

2004 | JOURNAL_ARTICLE

DOI: 10.1002/chem.200305376

EID: 2-s2.0-1842562954

Mostrar Detalles




Stability and kinetics of the acid-promoted decomposition of Cu(II) complexes with hexaazacyclophanes: kinetic studies as a probe to detect changes in the coordination mode of the macrocycles

2004 | JOURNAL_ARTICLE

DOI: 10.1039/b311772c

EID: 2-s2.0-85034314155

Parte de ISBN: 14779226

Mostrar Detalles




Synthesis and structure of the incomplete cuboidal clusters [W3Se4H3(dmpe)(3)](+), [W3Se4H3-x(OH)(x)(dmpe)(3)](+) and [W3Se4(OH)(3)(dmpe)(3)](+), and the mechanism of the acid-assisted substitution of the coordinated hydrides

2004 | JOURNAL_ARTICLE

DOI: 10.1039/b315841a

EID: 2-s2.0-1642347643

Parte de ISBN: 14779226

Mostrar Detalles




The Effect of the "Inert" Counteranions in the Deprotonation of the Dihydrogen Complex trans-[FeH(η2-H2)(dppe) 2]+: Kinetic and Theoretical Studies

2004 | JOURNAL_ARTICLE

DOI: 10.1021/ja039844j

EID: 2-s2.0-1542375005

Mostrar Detalles




Exploring the properties and optical sensing capability of sol-gel materials containing a covalently bonded binucleating cryptand

2003 | JOURNAL_ARTICLE

DOI: 10.1021/cm021337y

EID: 2-s2.0-0038474092

Mostrar Detalles




Hydrogen-ion driven molecular motions in Cu2+-complexes of a ditopic phenanthrolinophane ligand

2003 | JOURNAL_ARTICLE

DOI: 10.1039/b309721h

EID: 2-s2.0-0346880468

Parte de ISBN: 1364548X 13597345

Mostrar Detalles




Synthesis, equilibrium studies and structural characterisation of the Zn(II) complexes with trimethylene-N6,N6′-bisadenine

2003 | JOURNAL_ARTICLE

DOI: 10.1016/S0162-0134(02)00568-8

EID: 2-s2.0-0347298724

Mostrar Detalles




Thermodynamic and kinetic studies on the Cu2+ coordination chemistry of a novel binucleating pyridinophane ligand

2003 | JOURNAL_ARTICLE

DOI: 10.1039/b209013a

EID: 2-s2.0-12344285018

Mostrar Detalles




Equilibrium and kinetic studies on the formation of mono- and bi-nuclear Ni-II complexes with a binucleating hexaaza macrocycle

2002 | JOURNAL_ARTICLE

DOI: 10.1039/b205839c

Mostrar Detalles




Equilibrium and kinetic studies on the formation of mono- and bi-nuclear NiII complexes with a binucleating hexaaza macrocycle

2002 | JOURNAL_ARTICLE

EID: 2-s2.0-0035981326

Parte de ISBN: 1470479X

Mostrar Detalles




Reversible binuclear Cu(II) complex formation in a new sonogel-cryptand hybrid material

2002 | JOURNAL_ARTICLE

DOI: 10.1021/cm0111635

EID: 2-s2.0-0036195321

Mostrar Detalles




Stability and kinetics of the acid-promoted decomposition of tertiary binuclear (Cu2LXz+)-L-II complexes (L=octaaza cryptand, X=SCN-, N-3(-) and 2 NH3): the ancillary ligand modulates the kinetics of dissociation of the cryptand

2002 | JOURNAL_ARTICLE

DOI: 10.1039/b111573c

Mostrar Detalles




Stability and kinetics of the acid-promoted decomposition of tertiary binuclear CuII2LXZ+ complexes (L = octaaza cryptand, X = SCN-, N3- and 2 NH3): The ancillary ligand modulates the kinetics of dissociation of the cryptand

2002 | JOURNAL_ARTICLE

EID: 2-s2.0-0036247310

Parte de ISBN: 1470479X

Mostrar Detalles




Steady-state isotopic transient kinetic analysis of the H2/D2 exchange reaction as a tool for characterising the metal phase in supported platinum catalysts

2002 | JOURNAL_ARTICLE

DOI: 10.1016/S0926-860X(02)00077-7

EID: 2-s2.0-0037054078

Mostrar Detalles




Structurally different dinuclear copper(II) complexes with the same triazolopyrimidine bridging ligand

2002 | JOURNAL_ARTICLE

Mostrar Detalles




Structurally different dinuclear copper(II) complexes with the same triazolopyrimidine bridging ligand

2002 | JOURNAL_ARTICLE

DOI: 10.1002/1099-0682(200203)2002:4<811::AID-EJIC811>3.0.CO;2-9

EID: 2-s2.0-0036218291

Parte de ISBN: 14341948

Mostrar Detalles




Equilibrium studies on the protonation and Cu(II) complexation by an hexaaza macrocycle containing p-xylyl spacers. The crystal structure of the hexaprotonated ligand and the kinetics of decomposition of the Cu(II) complexes

2001 | JOURNAL_ARTICLE

DOI: 10.1016/S0277-5387(00)00630-6

EID: 2-s2.0-0035118097

Mostrar Detalles




Stability and kinetics of decomposition of binuclear Cu(II) complexes with a symmetrical hexaaza macrocycle: The effect of SCN- as ancillary ligand

2001 | JOURNAL_ARTICLE

DOI: 10.1016/S0277-5387(00)00589-1

EID: 2-s2.0-0035122427

Mostrar Detalles




Kinetics of formation of dihydrogen complexes by protonation of CpRuHL complexes (L = DPPM, DPPE, 2 PPh3) with HBF4 center dot Et2O in THF and the failure to observe dihydrogen complexes in the reactions with other acids

2000 | JOURNAL_ARTICLE

DOI: 10.1021/om9907775

Mostrar Detalles




Kinetics of formation of dihydrogen complexes by protonation of CpRuHL complexes (L = DPPM, DPPE, 2 PPh3) with HBF4·Et2O in THF and the failure to observe dihydrogen complexes in the reactions with other acids

2000 | JOURNAL_ARTICLE

EID: 2-s2.0-0000868322

Parte de ISBN: 02767333

Mostrar Detalles




The kinetics and mechanisms of reactions involving the dihydrogen complex trans-[FeH(H-2)(DPPE)(2)](+) and related compounds

2000 | JOURNAL_ARTICLE

DOI: 10.1016/S0022-328X(00)00350-8

EID: 2-s2.0-0002396961

Parte de ISBN: 0022328X

Mostrar Detalles




Kinetic studies on the reactions of macrocyclic complexes: formation of mono- and bi-nuclear copper(II) complexes with a binucleating hexaazamacrocycle in slightly acidic solutions

1999 | JOURNAL_ARTICLE

DOI: 10.1039/a809482i

EID: 2-s2.0-33748480649

Parte de ISBN: 03009246

Mostrar Detalles




Mechanisms of reactions of dihydrogen complexes: Formation of trans-[RuH(H-2)(dppe)(2)](+) and substitution of coordinated dihydrogen

1999 | JOURNAL_ARTICLE

DOI: 10.1021/ic9902267

Mostrar Detalles




Mechanisms of reactions of dihydrogen complexes: Formation of trans-[RuH(H2)(dppe)2]+ and substitution of coordinated dihydrogen

1999 | JOURNAL_ARTICLE

EID: 2-s2.0-0000575795

Parte de ISBN: 00201669

Mostrar Detalles




Molecular recognition of dipeptides. Catalysis of deuteration and hydrolysis of glycylglycine by dinuclear OBISDIEN Zn(II) complexes

1999 | JOURNAL_ARTICLE

Mostrar Detalles




Molecular recognition of dipeptides. Catalysis of deuteration and hydrolysis of glycylglycine by dinuclear OBISDIEN Zn(II) complexes

1999 | JOURNAL_ARTICLE

DOI: 10.1016/S0020-1693(98)00416-2

EID: 2-s2.0-0040611016

Parte de ISBN: 00201693

Mostrar Detalles




Solvent and incoming ligand effects on the mechanism of substitution reactions of trans-[FeH(L)(DPPE)(2)](+) (L = MeCN), and comparison with the dihydrogen analogue (L = H-2)

1999 | JOURNAL_ARTICLE

DOI: 10.1039/a905377h

EID: 2-s2.0-33749155236

Parte de ISBN: 03009246

Mostrar Detalles




Statistically controlled kinetics for the formation and decomposition of binuclear complexes of Cu-II with a large octaaza cryptand

1999 | JOURNAL_ARTICLE

DOI: 10.1039/a906029d

EID: 2-s2.0-33748512587

Parte de ISBN: 03009246

Mostrar Detalles




Kinetics and mechanism of substitution reactions in cis-[RuCl(L)-(dppe)(2)](+) complexes (L = RCN, dppe = Ph2PCH2CH2PPh2)

1998 | JOURNAL_ARTICLE

DOI: 10.1039/a804420a

Mostrar Detalles




Kinetics and mechanism of substitution reactions in cis-[RuCl(L)-(dppe)2]+ complexes (L = RCN, dppe = Ph2PCH2CH2PPh2)

1998 | JOURNAL_ARTICLE

EID: 2-s2.0-33748512804

Parte de ISBN: 03009246

Mostrar Detalles




Kinetics of formation of dihydrogen complexes: protonation of cis-[FeH2{P(CH2CH2PPh2)(3)} with acids in tetrahydrofuran

1998 | JOURNAL_ARTICLE

DOI: 10.1039/a707491c

EID: 2-s2.0-33749116408

Parte de ISBN: 03009246

Mostrar Detalles




Kinetics of protonation of cis-[FeH2(dppe)(2)]: formation of the dihydrogen complex trans-[FeH(H-2)(dppe)(2)](+) (dppe = Ph2PCH2-CH2PPh2)

1998 | JOURNAL_ARTICLE

DOI: 10.1039/a800916c

EID: 2-s2.0-33748515912

Parte de ISBN: 03009246

Mostrar Detalles




Unexpected Mechanism for Substitution of Coordinated Dihydrogen in trans-[FeH(H2)(DPPE)2]+

1998 | JOURNAL_ARTICLE

EID: 2-s2.0-0007004764

Parte de ISBN: 00201669

Mostrar Detalles




Unexpected mechanism for substitution of coordinated dihydrogen in trans-[FeH(H-2)(DPPE)(2)](+)

1998 | JOURNAL_ARTICLE

DOI: 10.1021/ic970493h

Mostrar Detalles




Equilibrium studies and molecular recognition in the glycylglycine, dl-alanyl-dl-alanine and glycyl-l-leucine Cu(II)-1,4,7,13,16,19-hexaaza-10,22-dioxacyclotetracosane complexes

1997 | JOURNAL_ARTICLE

Mostrar Detalles




Equilibrium studies and molecular recognition in the glycylglycine, dl-alanyl-dl-alanine and glycyl-l-leucine Cu(II)-1,4,7,13,16,19-hexaaza-10,22-dioxacyclotetracosane complexes

1997 | JOURNAL_ARTICLE

DOI: 10.1016/S0020-1693(96)05187-0

EID: 2-s2.0-0010853548

Parte de ISBN: 00201693

Mostrar Detalles




Kinetics of reaction of the Fe-II-cyclam complex with H2O2 in acetonitrile and the mechanism of catalyzed epoxidation of cyclohexene

1997 | JOURNAL_ARTICLE

DOI: 10.1016/S0277-5387(97)00144-7

EID: 2-s2.0-0039646537

Parte de ISBN: 02775387

Mostrar Detalles




Kinetics and mechanism of formation and decomposition of copper(II) complexes with a binucleating hexaazamacrocycle

1996 | JOURNAL_ARTICLE

Mostrar Detalles




Kinetics and mechanism of formation and decomposition of copper(II) complexes with a binucleating hexaazamacrocycle

1996 | JOURNAL_ARTICLE

DOI: 10.1016/0277-5387(96)00085-X

EID: 2-s2.0-0000502896

Parte de ISBN: 02775387

Mostrar Detalles




Kinetics of substitution reactions of Fe-II-phosphine complexes with Cl-, Br- and SCN- in acetonitrile. A comparative study of complexes containing bidentate and tripodal phosphines

1996 | JOURNAL_ARTICLE

Mostrar Detalles




Kinetics of substitution reactions of FeII-phosphine complexes with Cl-, Br- and SCN- in acetonitrile. A comparative study of complexes containing bidentate and tripodal phosphines

1996 | JOURNAL_ARTICLE

DOI: 10.1016/0277-5387(95)00512-9

EID: 2-s2.0-16144368487

Parte de ISBN: 02775387

Mostrar Detalles




FE-II COMPLEXES WITH TRIPOD PHOSPHINES, PH(2)PCH(2)CH(2)PPH(2) AND NET(3) - STABILITY AND KINETICS OF FORMATION

1995 | JOURNAL_ARTICLE

Mostrar Detalles




FeII complexes with tripod phosphines, Ph2PCH2CH2PPh2 and NEt3: Stability and kinetics of formation

1995 | JOURNAL_ARTICLE

DOI: 10.1016/0277-5387(94)00462-N

EID: 2-s2.0-27844587667

Parte de ISBN: 02775387

Mostrar Detalles




KINETICS OF SUBSTITUTION-REACTIONS OF TRANS-[MO(N2)2-(PPH2ME)4] WITH TRIPODAL PHOSPHINES

1994 | JOURNAL_ARTICLE

DOI: 10.1039/dt9940001717

Mostrar Detalles




Kinetics of substitution reactions of trans-[Mo(N2)2(PPh2Me)4] with tripodal phosphines

1994 | JOURNAL_ARTICLE

DOI: 10.1039/DT9940001717

EID: 2-s2.0-37049074109

Parte de ISBN: 14727773

Mostrar Detalles




SYNTHESIS AND KINETIC-STUDY OF PALLADIUM AND PLATINUM COMPLEXES WITH AMINOPOLYCARBOXYLATE LIGANDS

1994 | JOURNAL_ARTICLE

DOI: 10.1016/0277-5387(94)80007-3

EID: 2-s2.0-0006719079

Parte de ISBN: 02775387

Mostrar Detalles




CHEMISTRY OF COBALT COMPLEXES WITH 1,2-BIS-(DIETHYLPHOSPHINO)ETHANE - HYDRIDES, CARBON-DISULFIDE COMPLEXES, AND C-H CLEAVAGE IN ACTIVATED ALK-1-YNES - CRYSTAL-STRUCTURE OF [COH(CCCO2ET)(ET2PCH2CH2PET2)2]-[BPH4]

1993 | JOURNAL_ARTICLE

DOI: 10.1039/dt9930001841

Mostrar Detalles




Chemistry of cobalt complexes with 1,2-bis-(diethylphosphino)ethane: Hydrides, carbon disulfide complexes, and C-H cleavage in activated alk-1-ynes. Crystal structure of [CoH(C≡CCO2Et)(Et2PCH2CH 2PEt2)2][BPh4]

1993 | JOURNAL_ARTICLE

DOI: 10.1039/DT9930001841

EID: 2-s2.0-37049067526

Parte de ISBN: 14727773

Mostrar Detalles




DINITROGEN AND RELATED-COMPOUNDS OF MOLYBDENUM WITH THE TRIPODAL PHOSPHINES N(CH2CH2PPH2)3 OR P(CH2CH2PPH2)3 AS COLIGANDS

1993 | JOURNAL_ARTICLE

DOI: 10.1039/dt9930000923

Mostrar Detalles




Dinitrogen and related compounds of molybdenum with the tripodal phosphines N(CH2CH2PPh2)3 or P(CH2CH2PPh2)3 as coligands

1993 | JOURNAL_ARTICLE

DOI: 10.1039/DT9930000923

EID: 2-s2.0-37049075255

Parte de ISBN: 14727773

Mostrar Detalles




MECHANISM OF THE DECOMPOSITION REACTION OF TRANS-[MO(N2)2(PPH2ME)4] AND OF ITS REACTION WITH PYRIDINE

1992 | JOURNAL_ARTICLE

DOI: 10.1039/dt9920001291

Mostrar Detalles




Mechanism of the decomposition reaction of trans-[Mo(N2)2(PPh2Me)4] and of its reaction with pyridine

1992 | JOURNAL_ARTICLE

DOI: 10.1039/DT9920001291

EID: 2-s2.0-37049076974

Parte de ISBN: 14727773

Mostrar Detalles




An unexpected molybdenum(0) complex with "MoP6" coordination: crystal structure of [Mo{P(CH2CH2PPh2)3}2] · C5H10

1991 | JOURNAL_ARTICLE

DOI: 10.1016/0022-328X(91)86465-3

EID: 2-s2.0-0000890750

Mostrar Detalles




DISPLACEMENT OF TETRAHYDROFURAN LIGANDS BY TRIPODAL PHOSPHINES - CRYSTAL-STRUCTURE OF [MOCL3(N(CH2CH2PPH2)3)].C4H8O

1991 | JOURNAL_ARTICLE

DOI: 10.1039/dt9910003149

Mostrar Detalles




Displacement of tetrahydrofuran ligands by tripodal phosphines. Crystal structure of [MoCl3{N(CH2CH2PPh2) 3}]·C4H8O

1991 | JOURNAL_ARTICLE

DOI: 10.1039/DT9910003149

EID: 2-s2.0-37049077076

Parte de ISBN: 14727773

Mostrar Detalles




SYNTHESIS AND X-RAY STRUCTURAL STUDY OF A NOVEL RUTHENIUM(III) ETHYLENEDIAMINETETRAACETATE COMPLEX - THE 1ST COMPOUND SHOWING AN UNUSUAL COORDINATION SITE FOR A CARBOXYLIC (GLYCINE) GROUP

1991 | JOURNAL_ARTICLE

DOI: 10.1039/c39910000100

Mostrar Detalles




Synthesis and X-ray structural study of a novel ruthenium(III)- ethylenediaminetetraacetate complex. The first compound showing an unusual coordination site for a carboxylic (glycine) group

1991 | JOURNAL_ARTICLE

DOI: 10.1039/C39910000100

EID: 2-s2.0-37049068450

Parte de ISBN: 00224936

Mostrar Detalles




KINETICS AND MECHANISM OF THE DECOMPOSITION OF COBALT DIOXYGEN COMPLEXES OF THE BINUCLEATING MACROCYCLIC LIGAND BISBAMP

1989 | JOURNAL_ARTICLE

Mostrar Detalles




Kinetics and Mechanism of the Decomposition of Cobalt Dioxygen Complexes of the Binucleating Macrocyclic Ligand BISBAMP

1989 | JOURNAL_ARTICLE

DOI: 10.1021/ic00317a020

EID: 2-s2.0-0039246483

Parte de ISBN: 1520510X 00201669

Mostrar Detalles




NEW MULTIDENTATE LIGANDS .29. STABILITIES OF METAL-COMPLEXES OF THE BINUCLEATING MACROCYCLIC LIGAND BISBAMP AND DIOXYGEN AFFINITY OF ITS DINUCLEAR COBALT(II) COMPLEX

1988 | JOURNAL_ARTICLE

Mostrar Detalles




New Multidentate Ligands. 29. Stabilities of Metal Complexes of the Binucleating Macrocyclic Ligand BISBAMP and Dioxygen Affinity of Its Dinuclear Cobalt(II) Complex

1988 | JOURNAL_ARTICLE

DOI: 10.1021/ic00296a025

EID: 2-s2.0-33845280937

Parte de ISBN: 1520510X 00201669

Mostrar Detalles




SYNTHESIS, STRUCTURE AND PROPERTIES OF NEW RUTHENIUM COMPLEXES

1988 | JOURNAL_ARTICLE

Mostrar Detalles




H-1 AND C-13 NMR-SPECTRA OF PD(II) AND PT(II) AMINOPOLYCARBOXYLATES

1987 | JOURNAL_ARTICLE

DOI: 10.1016/S0277-5387(00)81026-8

EID: 2-s2.0-3242839577

Parte de ISBN: 02775387

Mostrar Detalles




Palladium and platinum guanine complexes

1986 | JOURNAL_ARTICLE

DOI: 10.1007/BF00619477

EID: 2-s2.0-0022740004

Mostrar Detalles




Ruthenium complexes as antitumor drugs: isolation of a new Ru (III) and iminodiacetic acid complex,Complejos de rutenio como drogas antitumorales: aislamiento de un nuevo compuesto de Ru (III) y AID.

1984 | JOURNAL_ARTICLE

EID: 2-s2.0-0021652450

Parte de ISBN: 0482640X

Mostrar Detalles




[Ruthenium complexes as antitumor drugs: isolation of a new Ru (III) and iminodiacetic acid complex].

1984 | JOURNAL_ARTICLE

Mostrar Detalles




SYNTHESIS AND CHARACTERIZATION OF NEW PALLADIUM COMPLEXES WITH PDTA

1983 | JOURNAL_ARTICLE

Mostrar Detalles




Thermal study of palladium complexes with trans-1,2-diaminecy clohexanetetraacetic acid

1983 | JOURNAL_ARTICLE

EID: 2-s2.0-48749143638

Mostrar Detalles




Coordination compounds of Pd(II) with potential antitumor activity,Compuestos de coordinación de Pd(II) con potencial actividad antitumoral.

1982 | JOURNAL_ARTICLE

EID: 2-s2.0-0020217247

Parte de ISBN: 0482640X

Mostrar Detalles




THERMAL-DECOMPOSITION OF PALLADIUM COMPLEXES WITH PROPYLENEDIAMINETETRAACETIC ACID

1982 | JOURNAL_ARTICLE

DOI: 10.1016/0040-6031(82)87106-2

Mostrar Detalles




Thermal decomposition of palladium complexes with propylenediaminetetraacetic acid

1982 | JOURNAL_ARTICLE

EID: 2-s2.0-49049144344

Mostrar Detalles




[Coordination compounds of Pd(II) with potential antitumor activity].

1982 | JOURNAL_ARTICLE

Mostrar Detalles